Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethylene → Ethene propene 1-butene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethylene | HCID 6325 | — |
| 반응물 | 1-Butene | HCID 7844 | — |
| 반응물 | Propylene | HCID 8252 | — |
| 반응물 | trans-2-BUTENE | HCID 62695 | — |
| 반응물 | Aluminum(III) Chloride | HCID 6451240 | — |
| 반응물 | Diethyl aluminum chloride | HCID 16686102 | — |
| 반응물 | HCID 178418361 | HCID 178418361 | — |
| 생성물 | Ethene propene 1-butene | HCID 168434 | — |
반응 단계
With the aid of a catalyst of 0.014 part by weight of the TiCl3 . 0.33 AlCl3 described in Example 1 and 0.022 part by weight of diethylaluminum chloride, 20 parts by weight of propene (99%) is polymerized under a pressure of 14-9 atm. gauge and a temperature of 70° C. after adding 0.00015 part by weight of hydrogen in 60 parts by weight of a butene-2-rich C4 -cut containing 0.4% of butene-1. After a polymerization period of 6 hours, 1.0 part by weight of ethene is introduced under pressure, and the polymerization is containued for another 4 hours. After passing the reaction mixture through nozzles in the presence of 0.1 part by weight of steam, a propene-ethene-butene-1 terpolymer is obtaining having the properties as shown in the Table.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US03959409 |
| 출처 데이터셋 | uspto-grants-1976_05 |
| ORD ID | ord-9aeb60ee197a472cb9c23c19d7d68caa |
| 출처 메모 | uspto-grants-1976_05 |