HuagongsheHuagongshe Chemistry Print Report · For research reference only
(3S,6S)-Octane-3,6-diol → 2,3-bis[(2R,5R)-2,5-diethyl-phospholan-1-yl)-benzo[b]thiophene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (3S,6S)-Octane-3,6-diol | HCID 7009316 | — |
| Reactant | 2,3-Bisphosphinobenzo[b]thiophene | HCID 11658457 | — |
| Product | 2,3-bis[(2R,5R)-2,5-diethyl-phospholan-1-yl)-benzo[b]thiophene | HCID 86595620 | 48% |
Reaction Steps
In analogy to Example 11, the cyclic sulfate derived from (3S,6S)-3,6-octanediol is reacted with 2,3-bisphosphinobenzo[b]thiophene to give the title compound in 48% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07094907B2 |
| Source dataset | uspto-grants-2006_08 |
| ORD ID | ord-c9e588b9fb2e4e3d96164ee2aa8ac6ed |
| Source note | uspto-grants-2006_08 |