N,N-Dimethylaniline → HCID 68131471, compound
Reaction equation
[CH3:1][N:2]([CH3:9])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[S:10](=[O:13])([OH:12])[OH:11]>>[S:10]([OH:13])([OH:12])=[O:11].[CH3:1][N:2]([CH3:9])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1Participants
Procedure
A gaseous mixture of gaseous dimethyl aniline, SO2 gas and steam leaves stripping section 30 of tower 31 and enters and passes upwardly within rectifying section 35. Substantially all dimethyl aniline is removed from such gaseous mixture in rectifying section 35 by absorption in dilute aqueous sulfurous acid solution flowing downwardly in rectifying section 35. The sulfurous acid solution is formed in rectifying section 35 due to the dissolution of a minor portion of the SO2 gas in liquid water resulting from condensation of all or virtually all of the steam. The gaseous dimethyl aniline reacts with the sulfurous acid in rectifying section 35 to form dimethyl aniline sulfite. Liquid aqueous solution containing sulfurous acid and dimethyl aniline sulfite is withdrawn from a lower portion of rectifying section 35 at an elevated temperature of 155°F. through line 40 and, after being indirectly cooled in cooler 93 with cooling water, is pumped at a temperature of 75°F. and a flow rate of 335 g.p.m. into the upper portion of rectifying section 35 above the uppermost tray therein through line 42.
Sources & evidence
- ORD record
- ord-02950d83bcb540f997e00ae539b45512
- Source dataset
- uspto-grants-1976_05
- Patent number
- US03959451
Reaction notes
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