Sodium Carbonate → HCID 21503901, compound

HRID 1077302Notes

Reaction equation

HRID 1077302 reaction equation
[CH:1]1[C:14]2[C:13](=[O:15])[C:12]3[C:7](=[CH:8][C:9]([C:16]([OH:18])=[O:17])=[CH:10][CH:11]=3)[C:6](=[O:19])[C:5]=2[CH:4]=[CH:3][C:2]=1[C:20]([OH:22])=[O:21].C(=O)([O-])[O-].[Na+:27].[Na+]>>[CH:1]1[C:14]2[C:13](=[O:15])[C:12]3[C:7](=[CH:8][C:9]([C:16]([O-:18])=[O:17])=[CH:10][CH:11]=3)[C:6](=[O:19])[C:5]=2[CH:4]=[CH:3][C:2]=1[C:20]([O-:22])=[O:21].[Na+:27].[Na+:27]

Participants

3

Reactant 2

HCID 10340Sodium CarbonateHCID 3918212HCID 3918212, compound

Product 1

HCID 21503901HCID 21503901, compound

Procedure

Anthraquinone-2,6-dicarboxylic acid (0.50g) was dissolved in sodium carbonate solution (1 equivalent of sodium carbonate, 0.18g, in water, 100 ml) with warming. As the di-sodium salt did not separate on cooling, the solution was evaporated to approximately 1/3 volume and heavily diluted with ethanol. The solid which separated was filtered off, dried at 100°C. and analysed for the dihydrate. Analysis: Required Carbon 51.09, Hydrogen 2.68, Found Carbon 50.67, Hydrogen 2.78.

Workup

  1. temperaturewith warming
  2. customAs the di-sodium salt did not separate
  3. temperatureon cooling
  4. customthe solution was evaporated to approximately 1/3 volume
  5. additionheavily diluted with ethanol
  6. customThe solid which separated
  7. filtrationwas filtered off
  8. customdried at 100°C.

Sources & evidence

ORD record
ord-54495c0781754fadbf010b09acb48fb0
Source dataset
uspto-grants-1976_05
Patent number
US03959482

Reaction notes

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