HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylamine → 3-(Ethylamino)-1,2,3,4-tetrahydrocarbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylamine | HCID 6341 | — |
| Reactant | 3-Tosyloxy-1,2,3,4-tetrahydrocarbazole | HCID 12361769 | — |
| Reactant | N-(2,3,4,9-Tetrahydro-1H-carbazol-3-YL)acetamide | HCID 12361788 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Product | 3-(Ethylamino)-1,2,3,4-tetrahydrocarbazole | HCID 12361770 | — |
Reaction Steps
Following the procedure given in Example 18 and using 25 g. of 3-tosyloxy-1,2,3,4- -tetrahydrocarbazole and 90 g. of ethylamine there was otained 3 g. of 3l -(ethylaino)-1,2,3,4-tetraydrocarbazole which melted at 128°-129°C. (corr.). Alternatively this compound can be prepared by reduction of 3-acetamido-1,2,3,4-tetrahydrocarbazole (Example 2) with lithium aluminum hydride following a procedure similar to that described in Example 260 below.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03959309 |
| Source dataset | uspto-grants-1976_05 |
| ORD ID | ord-67c2f8590d5c429dbc4057777785407e |
| Source note | uspto-grants-1976_05 |