Potassium Hydroxide → HCID 12891824, compound

HRID 1077345Notes

Reaction equation

HRID 1077345 reaction equation
C([O:9][CH:10]1[CH2:22][C:21]2[C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[N:14]([CH3:23])[C:13]=2[CH2:12][CH2:11]1)(=O)C1C=CC=CC=1.[OH-].[K+].OC1CC2C3C(=CC=C(C)C=3)NC=2CC1>>[OH:9][CH:10]1[CH2:22][C:21]2[C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[N:14]([CH3:23])[C:13]=2[CH2:12][CH2:11]1

Participants

4

Reactant 3

HCID 14797Potassium HydroxideHCID 12891783HCID 12891783, compoundHCID 23470297HCID 23470297, compound

Product 1

HCID 12891824HCID 12891824, compound

Procedure

The 3-hydroxy-9-methyl-1,2,3,4-tetrahydrocarbazole was prepared by hydrolysis of 9.1 g. of 3-benzoyloxy-9-methyl-1,2,3,4-tetrahydrocarbazole and 1.95 g. of potassium hydroxide in 100 ml. of 50% ethaol using the procedure described in Example 21 for the preparation of 3-hydroxy-6-methyl-1,2,3,4-tetrahydrocarbazole. There was thus otained 48 g. of 3l -hydroxy-9-methyl-1,2,3,4-tetrahydrocarbazole which melted at 104°-106°C.

Sources & evidence

ORD record
ord-de082d5d96604c57928eb5c1a558b05d
Source dataset
uspto-grants-1976_05
Patent number
US03959309

Reaction notes

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