Methyl iodide → 3-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,6-dimethylpyridinium iodide

HRID 1077819Notes

Reaction equation

HRID 1077819 reaction equation
[CH3:1][I:2].[CH2:3]([S:9][C:10]1[C:14]([C:15]2[CH:16]=[N:17][C:18]([CH3:21])=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)[CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>CC(C)=O>[I-:2].[CH2:3]([S:9][C:10]1[C:14]([C:15]2[CH:16]=[N+:17]([CH3:1])[C:18]([CH3:21])=[CH:19][CH:20]=2)=[N:13][S:12][N:11]=1)[CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 190753693-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-6-methylpyridine

Product 1

HCID 190753283-(3-Hexylthio-1,2,5-thiadiazol-4-yl)-1,6-dimethylpyridinium iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Methyl iodide (1 ml, 15 mmol) was added to a solution of 3-(3-hexylthio-1,2,5-thiadiazol-4-yl)-6-methylpyridine (4 mmol) in acetone (5 ml) and the reaction mixture was stirred at room temperature for 20 h. Evaporation of the reaction mixture gave the crude product, which was used without further purification.

Workup

  1. customEvaporation of the reaction mixture

Sources & evidence

ORD record
ord-b902f25fb1ed4c1ebeb41ff37d681a5a
Source dataset
uspto-grants-1996_08
Patent number
US05545638

Reaction notes

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