HRID1077983

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID31229

Phenyl acetate

C8H8O2

结构：O=C([O-])c1ccccc1Oc1ccc(C(F)(F)F)cc1NS(=O)(=O)c1cc(C(F)(F)F)cc(C(F)(F)F)c1.OC(c1ccccc1)c1ccccc1

HCID131719489

未命名化合物

PRODUCTS

生成物

结构：O=C(O)Cc1ccccc1Oc1ccc(C(F)(F)F)cc1NS(=O)(=O)c1cc(C(F)(F)F)cc(C(F)(F)F)c1

HCID19430539

未命名化合物

PROCEDURE

实验过程

Following the procedure of Example 1(f) except substituting benzhydrol 2-[3,5-bis (trifluoromethyl)phenylsulfonamido]-4-trifluoromethylphenoxy]phenyl acetate for benzhydrol 2-[2-[3,5-bis(trifluoromethyl)phenylsulfonamido]-4-trifluoromethylphenoxy]benzoate, the title compound was obtained; mp 165°-166° C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-fc5eeb47ed024c5eb24558e9aab8a54d
来源数据集: uspto-grants-1996_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05545669
来源说明: uspto-grants-1996_08

反应 SMILES

[C:1]([O:4]C1C=CC=CC=1)(=[O:3])[CH3:2].C(O)(C1C=CC=CC=1)C1C=CC=CC=1.[F:25][C:26]([F:62])([F:61])[C:27]1[CH:28]=[C:29]([S:37]([NH:40][C:41]2[CH:56]=[C:55]([C:57]([F:60])([F:59])[F:58])[CH:54]=[CH:53][C:42]=2[O:43][C:44]2[CH:52]=[CH:51][CH:50]=[CH:49][C:45]=2C([O-])=O)(=[O:39])=[O:38])[CH:30]=[C:31]([C:33]([F:36])([F:35])[F:34])[CH:32]=1>>[F:35][C:33]([F:36])([F:34])[C:31]1[CH:30]=[C:29]([S:37]([NH:40][C:41]2[CH:56]=[C:55]([C:57]([F:59])([F:60])[F:58])[CH:54]=[CH:53][C:42]=2[O:43][C:44]2[CH:52]=[CH:51][CH:50]=[CH:49][C:45]=2[CH2:2][C:1]([OH:4])=[O:3])(=[O:38])=[O:39])[CH:28]=[C:27]([C:26]([F:61])([F:62])[F:25])[CH:32]=1