Vinylidene fluoride → 1,1-Difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene

Participants

Reaction Steps

As noted above, we prefer to cover at least a portion of the sensor section (102), distal section (104), mid-section (106), or proximal section (108) with a fluoropolymeric composition comprising a copolymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride or an alloy or mixture of the three. Especially suitable are the series of fluoroplastics known as "THV Fluoroplastics" produced by 3M, particularly THV 200, THV 300, THV 400, and THV 500. Preferred compositions include those which have a melting range between about 115° and 180° C. (by DSC), a melt flow index of 5 to 25 (ASTM 1238), a specific gravity of 1.95-1.98 g/cc (ASTM 792), and elongation at breakage of 500-600% (ASTM 638). Such polymeric compositions are shown, for other uses, in U.S. Pat. No. 4,991,932, U.S. Pat. No. 4,979,799, U.S. Pat. No. 4,986,630, to Herbrects et al; U.S. Pat. No. 4,829,116, and U.S. Pat. No. 4,556,589. The polymeric composition is preferably placed onto the catheter by first extruding the polymeric composition into suitably sized tubing, at least partially cross-linking the polymer (often using radiation such as electron beam), placing the polymer about the catheter, and heating the polymer to shrink it onto the catheter body.

Provenance & Evidence