Trichlorosilane → Dichlorosilane

HRID 1079043Notes

Reaction equation

HRID 1079043 reaction equation
[Cl:1][SiH:2](Cl)[Cl:3].[CH2:5]([N:7]([CH2:15][CH3:16])[CH2:8][CH2:9][N:10]([CH2:13][CH3:14])[CH2:11][CH3:12])[CH3:6]>C(Cl)Cl>[Cl:1][SiH2:2][Cl:3].[CH2:13]([N:10]([CH2:11][CH3:12])[CH2:9][CH2:8][N:7]([CH2:15][CH3:16])[CH2:5][CH3:6])[CH3:14]

Participants

5

Reactant 2

HCID 24811TrichlorosilaneHCID 67423N,N,N',N'-Tetraethylethylenediamine List Acronyms

Product 2

HCID 61330DichlorosilaneHCID 67423N,N,N',N'-Tetraethylethylenediamine List Acronyms

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

The ability of trichlorosilane to redistribute in the presence of tetraethylethylenediamine (TEEDA) and methylene chloride to form a complex comprising dichlorosilane and TEEDA was evaluated. All reactions were performed in a glass flask under a blanket of dry nitrogen. Trichlorosilane was distilled before use. TEEDA was dried by refluxing over CaH2 and then distilled. Dichloromethane was distilled from P2O5 just prior to use. The volumes of materials placed in the flask are provided in Table 1. Materials were added to the flask through a rubber septum by means of a syringe.

Sources & evidence

ORD record
ord-1ad32c522e4a4fb998e8fed9fc5e0056
Source dataset
uspto-grants-1996_08
Patent number
US05550269

Reaction notes

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