Sulfuryl chloride → HCID 15390497, compound

HRID 1080384Notes

Reaction equation

HRID 1080384 reaction equation
[F:1][CH:2]([F:25])[O:3][C:4]1[N:8]([CH3:9])[N:7]=[C:6]([N:10]2[C:14]([NH:15][C:16](=[O:21])[C:17]([F:20])([F:19])[F:18])=[C:13]([N+:22]([O-:24])=[O:23])[CH:12]=[N:11]2)[CH:5]=1.S(Cl)([Cl:29])(=O)=O>ClCCl>[Cl:29][C:5]1[C:6]([N:10]2[C:14]([NH:15][C:16](=[O:21])[C:17]([F:20])([F:19])[F:18])=[C:13]([N+:22]([O-:24])=[O:23])[CH:12]=[N:11]2)=[N:7][N:8]([CH3:9])[C:4]=1[O:3][CH:2]([F:1])[F:25]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 15390496HCID 15390496, compound

Product 1

HCID 15390497HCID 15390497, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

0.79 g (2.1 mmol) N-[1-(5-Difluoromethoxy-1-methyl-3-pyrazolyl)-4-nitro-5-pyrazolyl]-2,2,2-trifluoroacetamide was suspended in 35 ml dichloromethane and treated with 0.17 ml sulfuryl chloride. The mixture was stirred for one hour at room temperature and concentrated.

Workup

  1. concentrationconcentrated

Sources & evidence

ORD record
ord-45c203aa95a747b9921e201e0f7c6b0c
Source dataset
uspto-grants-1996_12
Patent number
US05580986

Reaction notes

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