Chlorine → HCID 53829400, compound

HRID 1081301Notes

Reaction equation

HRID 1081301 reaction equation
[N+:1]([C:4]1[CH:10]=[C:9]([S:11]([C:14]([F:17])([F:16])[F:15])(=[O:13])=[O:12])[CH:8]=[CH:7][C:5]=1[NH2:6])([O-:3])=[O:2].[Cl:18]Cl>C(O)(=O)C>[N+:1]([C:4]1[CH:10]=[C:9]([S:11]([C:14]([F:17])([F:15])[F:16])(=[O:13])=[O:12])[CH:8]=[C:7]([Cl:18])[C:5]=1[NH2:6])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 24526ChlorineHCID 45294692-Nitro-4-(trifluoromethanesulfonyl)aniline

Product 1

HCID 53829400HCID 53829400, compoundYield 95.3%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

In analogy to Example 14, 27 g of 2-nitro-4-trifluoromethylsulphonyl-aniline in 100 ml of acetic acid were chlorinated with 10 g of chlorine. 29 g of 2-nitro4-trifluoromethylsulphonyl-6-chloro-aniline were obtained; melting point 138°-139° C.

Sources & evidence

ORD record
ord-e203ac46e52344d9baaa1247f6183329
Source dataset
uspto-grants-1996_12
Patent number
US05585395

Reaction notes

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