Acetylene → HCID 11830456, compound

HRID 1081970Notes

Reaction equation

HRID 1081970 reaction equation
[CH3:1][Si:2]([CH3:11])([CH3:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][OH:9].[OH-].[K+].[CH:14]#[CH:15]>CS(C)=O>[CH:14]([O:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][Si:2]([CH3:1])([CH3:10])[CH3:11])=[CH2:15]

Participants

5

Reactant 3

HCID 6326AcetyleneHCID 14797Potassium HydroxideHCID 108884281-Hexanol, 6-(trimethylsilyl)-

Product 1

HCID 11830456HCID 11830456, compoundYield 99%

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

In a similar manner to Example 1, 75 g (0.43 mol) of 6-(trimethylsilyl)hexanol, 7.5 g of KOH and 75 g of DMSO were reacted at 80° C. with acetylene. 6-(Trimethylsilyl)hexyl vinyl ether was obtained in 99% yield.

Sources & evidence

ORD record
ord-72b075e6647b44a6bf2ed5412c09cce7
Source dataset
uspto-grants-1996_12
Patent number
US05587503

Reaction notes

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