Bicarbonate Ion → Tert-butyl-[5-(3-chloro-1-benzothiophen-2-yl)-1-iodopent-1-en-3-yl]oxy-dimethylsilane

HRID 108502Notes

Reaction equation

HRID 108502 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[O:8][CH:9]([C:10]#[CH:11])[CH2:12][CH2:13][c:14]1[c:15]([Cl:23])[c:16]2[c:17]([s:18]1)[cH:19][cH:20][cH:21][cH:22]2.[C:32](=[O:33])([OH:34])[O-:35].[Cl:37][CH2:38][Cl:39].[I:24][N:25]1[C:26](=[O:27])[CH2:28][CH2:29][C:30]1=[O:31].[Na+:36]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[O:8][CH:9]([CH:10]=[CH:11][I:24])[CH2:12][CH2:13][c:14]1[c:15]([Cl:23])[c:16]2[c:17]([s:18]1)[cH:19][cH:20][cH:21][cH:22]2

Participants

6

Reactant 5

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 6344DichloromethaneHCID 120273N-IodosuccinimideHCID 21964439tert-Butyl-{1-[2-(3-chloro-benzo[b]thiophen-2-yl)-ethyl]-prop-2-ynyloxy}-dimethylsilane

Product 1

HCID 73856872Tert-butyl-[5-(3-chloro-1-benzothiophen-2-yl)-1-iodopent-1-en-3-yl]oxy-dimethylsilane

Sources & evidence

ORD record
ord-bbfaa36e3d474594aeffa86ffc9735d2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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