참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Ethylenediaminetetraacetic Acid | HCID 6049 | — |
| 반응물 | Azobisisobutyronitrile | HCID 6547 | — |
| 반응물 | Acrylamide | HCID 6579 | — |
| 반응물 | Acrylic Acid | HCID 6581 | — |
| 반응물 | Potassium Hydroxide | HCID 14797 | — |
| 반응물 | Sodium Pyrosulfite | HCID 656671 | — |
| 반응물 | Potassium Bromate | HCID 23673461 | — |
| 반응물 | Span #80 (Sorbitan monooleate) | HCID 70693544 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | Potassium;prop-2-enamide;prop-2-enoate | HCID 16212816 | — |
반응 단계
The copolymer may be manufactured as follows: a water phase containing 199.1 g of acrylamide, 84.5 g of acrylic acid, 3.0 g of ethylenediaminetetraacetic acid, 0.2 g of potassium bromate, 60.3 g of potassium hydroxide and 342 g of water is homogenized with an oil phase containing 240 g of oil, 20 g of sorbitan monooleate, 0.2 g of 2,2'-azobis-(isobutyronitrile). The emulsion is then transferred to a suitable reaction vessel with stirring and is sparged with nitrogen. Polymerization is initiated and sustained by continuously adding a solution of sodium metabisulfite throughout the exotherm. The cooling is provided to maintain the temperature of the system between 35° C.-45° C. The polymerization is completed in about 6-10 hours to give an emulsion product of acrylamide/potassium acrylate copolymer. To produce a self-inverting product, 24 g of a breaker system composed of a 1.75:1 blend of the reaction product of nonylphenol with 6 moles of ethylene oxide and the reaction product of dinonylphenol with 24 moles of ethylene oxide is added.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US05007481 |
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| 출처 데이터셋 | uspto-grants-1991_04 |
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| ORD ID | ord-b13754e973c04a20ad1b1c71650c5be6 |
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| 출처 메모 | uspto-grants-1991_04 |
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