HuagongsheHuagongshe Chemistry Print Report · For research reference only
18-Crown-6 → 6-{4-[2-(4-Nitrophenyl)ethenyl]phenoxy}hexan-1-OL
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 18-Crown-6 | HCID 28557 | — |
| Reactant | 6-Iodo-1-hexanol | HCID 13089081 | — |
| Reactant | 4-Hydroxy-4'-nitrostilbene potassium salt | HCID 67920106 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 6-{4-[2-(4-Nitrophenyl)ethenyl]phenoxy}hexan-1-OL | HCID 53938164 | — |
Reaction Steps
To 500 ml of toluene in a one liter round bottom flask, fitted with a condenser and magnetic stirrer, is added 14 g (0.05M) of 4-hydroxy-4'-nitrostilbene potassium salt, 14 g of 6-iodo-1-hexanol, and 0.5 g of 18-crown-6 ether. The mixture is refluxed for about 20 hours, and then the reaction medium is filtered hot, and the product crystallizes from the toluene on cooling, m.p. 154°-157° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05007696 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-81b3e28c6a9c4a49b9964b1cb46a761f |
| Source note | uspto-grants-1991_04 |