HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → 3-Cycloheptylpropanenitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | Acrylonitrile | HCID 7855 | — |
| Reactant | Bromocycloheptane | HCID 16992 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 3-Cycloheptylpropanenitrile | HCID 13164045 | — |
Reaction Steps
3-Cycloheptylpropionitrile is prepared in this example according to the procedure of Example 1 using a solution of 2-bromocycloheptane (25.57 g; 144.38 mmole); Bu3SnH (50.42 g; 173.26 mmole), acrylonitrile (15.32 g; 288.77 mmole), and AIBN (1.13 g) in toluene (300 ml). Yield is 16 g; mp oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05008265 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-8e7da019e32f41f4baaf4eadfa9ecce2 |
| Source note | uspto-grants-1991_04 |