HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Iodide → 2-Methylbutyl 4'-(6-hydroxyhexyloxy)biphenyl-4-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Iodide | HCID 4875 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 6-Chloro-1-hexanol | HCID 74828 | — |
| Reactant | 2-Methylbutyl 4'-hydroxybiphenyl-4-carboxylate | HCID 13907537 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2-Methylbutyl 4'-(6-hydroxyhexyloxy)biphenyl-4-carboxylate | HCID 20058820 | 34.1% |
Reaction Steps
2.84 g of 2-methylbutyl 4'-hydroxybiphenyl-4-carboxylate, 4.14 g of potassium carbonate, 4.10 g of 6-chloro-1-hexanol and 4.28 g of potassium iodide were heat-refluxed for 48 hours in acetone. The mixture was subjected to filtration, condensation and purification by column chromatography to obtain 1.31 g of the objective product (yield: 34%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05011623 |
| Source dataset | uspto-grants-1991_04 |
| ORD ID | ord-1a1e807bed6f49adba1260129a0ac7ed |
| Source note | uspto-grants-1991_04 |