Cyanuric fluoride → HCID 53911301, compound

HRID 1086763Notes

Reaction equation

HRID 1086763 reaction equation
[F-:1].[Cs+].[O:3]([C:10]([F:17])=[C:11]([F:16])[C:12]([F:15])([F:14])[F:13])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1.[N:18]1[C:25]([F:26])=[N:24][C:22](F)=[N:21][C:19]=1[F:20]>>[F:20][C:19]1[N:18]=[C:25]([F:26])[N:24]=[C:22]([C:11]([F:16])([C:12]([F:13])([F:14])[F:15])[C:10]([F:1])([F:17])[O:3][C:4]2[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=2)[N:21]=1

Participants

4

Reactant 3

HCID 12664Cyanuric fluorideHCID 25953Cesium fluorideHCID 54276397HCID 54276397, compound

Product 1

HCID 53911301HCID 53911301, compoundYield 83.5%

Procedure

One g (0.1 mole) of CsF and 22 g (0.1 mole) of 1-phenoxy perfluoropropene and 10 g (0.1 mole) of cyanuric fluoride are placed into a Parr bomb. The bomb is sealed and stirred at 100°-130° C. for 16 hours. After cooling, the solids are filtered off and 30 g of oil are obtained. This is distilled to produce the product compound as an oil with a boiling point of 195° C. in a yield of 39 percent.

Workup

  1. customThe bomb is sealed
  2. temperatureAfter cooling
  3. filtrationthe solids are filtered off

Sources & evidence

ORD record
ord-37cb618fc1844a009769740c36586552
Source dataset
uspto-grants-1991_07
Patent number
US05032301

Reaction notes

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