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HRID1086778

反应详情

EQUATION

反应方程式

HRID 1086778 的结构方程式

REACTANTS

反应物

3
结构：O
HCID962

Water

H2O

结构：CC(C)=O.O=S(=O)(O)O.[O]=[Cr](=[O])=[O]
HCID131709961

未命名化合物

结构：CCCCC[C@H]1CC[C@H](/C=C/COc2ccc(C=O)cc2)CC1
HCID178444466

未命名化合物

PRODUCTS

生成物

1
结构：CCCCC[C@H]1CC[C@H](/C=C/COc2ccc(C(=O)O)cc2)CC1
HCID178444468

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

PROCEDURE

实验过程

A solution of 4 g of 4-[(E)-3-(trans-4-pentylcyclohexyl)allyloxy]benzaldehyde (Prepared according to Example 3) in 100 ml of acetone was treated dropwise with 10 ml of Jones' reagent. The mixture was stirred at room temperature for 1 hour and then poured into 100 ml of water. The preciPitate which thereby resulted was filtered off, washed portionwise with water and dried in a vacuum. The crude product was recrystallized from ethanol and gave 2,5 g of pure 4-[(E)-3-(trans-4-pentylcyclohexyl)allyloxy]benzoic acid; m.p. 214-215° C..

WORKUP

后处理

  1. customThe preciPitate which thereby resulted
  2. filtrationwas filtered off
  3. washwashed portionwise with water
  4. customdried in a vacuum
  5. customThe crude product was recrystallized from ethanol