HuagongsheHuagongshe Chemistry Print Report · For research reference only
(1,4-Dioxaspiro[4.5]decan-8-ylidene)acetonitrile → 1,4-Dioxaspiro[4.5]decane-8-acetonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (1,4-Dioxaspiro[4.5]decan-8-ylidene)acetonitrile | HCID 22624677 | — |
| Catalyst | Platinum oxide (PtO) | HCID 82844 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1,4-Dioxaspiro[4.5]decane-8-acetonitrile | HCID 10241426 | — |
Reaction Steps
The above nitrile (2.15 g) is treated with platinum oxide (0.1 g) in ethanol (200 ml) and hydrogenated at 3 atmospheres pressure over 4 hours. Removal of the catalyst and concentration of the solvent gives 8-cyanomethyl-1,4-dioxaspiro[4.5]decane as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05034381 |
| Source dataset | uspto-grants-1991_07 |
| ORD ID | ord-20b26b7cc5964f09a5be810b2bb97fa7 |
| Source note | uspto-grants-1991_07 |