(Chloromethyl)triphenylphosphonium chloride → HCID 54509772, compound

HRID 1087396Notes

Reaction equation

HRID 1087396 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[CH:9]([CH3:18])[C:10]([C:12]1[CH:13]=[N:14][CH:15]=[CH:16][CH:17]=1)=O.[Cl-].[Cl:20][CH2:21][P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1>>[Cl:20][CH:21]=[C:10]([C:12]1[CH:13]=[N:14][CH:15]=[CH:16][CH:17]=1)[CH:9]([CH3:18])[C:3]1[CH:4]=[CH:5][C:6]([Cl:8])=[CH:7][C:2]=1[Cl:1]

Participants

3

Reactant 2

HCID 197823(Chloromethyl)triphenylphosphonium chlorideHCID 140744312-(2,4-Dichlorophenyl)-1-(3-pyridyl)-1-propanone

Product 1

HCID 54509772HCID 54509772, compound

Procedure

starting from 2-(2,4-dichlorophenyl)-1-(3-pyridyl)-1-propanone and chloromethyltriphenylphosphonium chloride there is obtained 3-(α-chloromethylene-2,4-dichloro-β-methylphenethyl)-pyridine as an isomer-pure compound in the form of a yellow oil;

Sources & evidence

ORD record
ord-6e9cbb3ba67945eca4c8641ddc26f7df
Source dataset
uspto-grants-1991_07
Patent number
US05036074

Reaction notes

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