Methoxymethyl-triphenylphosphonium chloride → HCID 54371957, compound

HRID 1087402Notes

Reaction equation

HRID 1087402 reaction equation
[N:1]1[CH:6]=[CH:5][CH:4]=[C:3]([C:7]2([C:10]([C:12]3[CH:17]=[CH:16][C:15]([Cl:18])=[CH:14][C:13]=3[Cl:19])=O)[CH2:9][CH2:8]2)[CH:2]=1.[Cl-].[CH3:21][O:22][CH2:23][P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1>>[Cl:19][C:13]1[CH:14]=[C:15]([Cl:18])[CH:16]=[CH:17][C:12]=1[C:10]([C:7]1([C:3]2[CH:2]=[N:1][CH:6]=[CH:5][CH:4]=2)[CH2:9][CH2:8]1)=[CH:21][O:22][CH3:23]

Participants

3

Reactant 2

HCID 2723798Methoxymethyl-triphenylphosphonium chlorideHCID 198170702,4-Dichlorophenyl 1-(3-pyridyl)-cyclopropyl ketone

Product 1

HCID 54371957HCID 54371957, compound

Procedure

starting from 2,4-dichlorophenyl 1-(3-pyridyl)-cyclopropyl ketone and methoxymethyltriphenylphosphonium chloride there is obtained 3-[1-(2,4-dichloro-α-methoxymethylenebenzyl)-cyclopropyl]-pyridine as an isomer mixture in the form of a yellow oil;

Sources & evidence

ORD record
ord-cfe0074c656c44dc8553bdd2dd7e9442
Source dataset
uspto-grants-1991_07
Patent number
US05036074

Reaction notes

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