HCID 14746146, compound → HCID 14746147, compound

HRID 1088000Notes

Reaction equation

HRID 1088000 reaction equation
[OH:1][CH2:2][CH2:3][S:4]([CH2:7][C:8]1[CH:13]=[CH:12][C:11]([CH2:14][S:15]([CH2:18][CH2:19][OH:20])(=[O:17])=[O:16])=[CH:10][C:9]=1[N+:21]([O-])=O)(=[O:6])=[O:5]>[Pd]>[OH:1][CH2:2][CH2:3][S:4]([CH2:7][C:8]1[CH:13]=[CH:12][C:11]([CH2:14][S:15]([CH2:18][CH2:19][OH:20])(=[O:17])=[O:16])=[CH:10][C:9]=1[NH2:21])(=[O:6])=[O:5]

Participants

3

Reactant 1

HCID 14746146HCID 14746146, compound

Product 1

HCID 14746147HCID 14746147, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

The procedure as described in Examples 13 and 14 is repeated, using each time 150 parts of 2,5-bis(hydroxyethylsulfonylmethyl)nitrobenzene as well as each time the aqueous mother liquor and the palladium catalyst of the previous batch to give each time about 128 parts of 2,5-bis(hydroxyethylsulfonylmethyl)aniline of melting point 197° to 199° C. and a purity (diazotization) of >99%, i.e., mother liquor and catalyst can each be recycled at least 10 times without deterioration of the product or reduction of the yield.

Sources & evidence

ORD record
ord-071624674c7f4fbabaace8cbd0f7dde0
Source dataset
uspto-grants-1990_10
Patent number
US04960940

Reaction notes

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