HuagongsheHuagongshe Chemistry Print Report · For research reference only
Silanol, 1,1,1-triethyl-, 1-acetate → Hexaethyldisiloxane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Silanol, 1,1,1-triethyl-, 1-acetate | HCID 79173 | — |
| Reactant | pyridine-4-thiol | HCID 178418431 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | Hexaethyldisiloxane | HCID 70442 | — |
Reaction Steps
This solution of resulting mesylate (4) is mixed with 4-mercaptopyridine (803 mg; 1.25 equivalents) and acetonitrile (22 ml), warmed to room temperature, and stirred for 2 hours to give a solution of pyridylsulfide (7).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04960879 |
| Source dataset | uspto-grants-1990_10 |
| ORD ID | ord-7aae61c5e8ba4dba8d21bb8dfccbb991 |
| Source note | uspto-grants-1990_10 |