HRID1088413

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID10470

Octacosanoic acid

C28H56O2

HCID42953

3,3'-Oxydi(propane-1,2-diol)

C6H14O5

HCID5352426

Tin atom

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCCCCCCCCCCCCCCC(=O)O.OCC(O)CO.OCC(O)CO

HCID131716646

未命名化合物

CONDITIONS

反应条件

温度: 100 °C

PROCEDURE

实验过程

112 g diglycerol (0.67 mole), 400 g montanic acid (1.0 mole) and 0.4 g tin powder were heated to 200° C. as in Example 1 with application of a gentle vacuum. The vacuum was increased to 24 mbar over a period of 3.4 h. The product had an acid value of approximately 1. A brown colored hard wax having a dropping point of 81° C. was obtained after cooling to 100° C., bleaching and filtering.

WORKUP

后处理

temperatureThe vacuum was increased to 24 mbar over a period of 3.4 h
customa dropping point of 81° C.
customwas obtained
filtrationfiltering

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8242717f30c14ddebc0995dac6a68de3
来源数据集: uspto-grants-1990_10
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04962145
来源说明: uspto-grants-1990_10

反应 SMILES

C(O)C(O)C[O:4][CH2:5][CH:6]([OH:9])[CH2:7][OH:8].[C:12]([OH:41])(=[O:40])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].[Sn]>>[C:12]([OH:41])(=[O:40])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9].[OH:4][CH2:5][CH:6]([CH2:7][OH:8])[OH:9]