Benzene → HCID 14494006, compound

HRID 1088516Notes

Reaction equation

HRID 1088516 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)(=O)[CH3:2].[Cl:10][C:11]1[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=1[NH2:13].C1C=CC=CC=1>O>[Cl:10][C:11]1[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=1[N:13]=[C:1]([CH3:2])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1

Participants

5

Reactant 3

HCID 241BenzeneHCID 72402-ChloroanilineHCID 7410Acetophenone

Product 1

HCID 14494006HCID 14494006, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of acetophenone (130 ml), 2-chloroaniline (130 ml) and benzene (200 ml) was refluxed in the presence of molecular sieve with continuous removal of water. o-Chloro-N-(α-methyl benzylidene) aniline (XXI) was obtained by fractional distillation. XXI had a boiling point of 111° C. at 0.1 millimeter.

Sources & evidence

ORD record
ord-82536c548eeb4f78a9fd0784f1379e3c
Source dataset
uspto-grants-1990_10
Patent number
US04962234

Reaction notes

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