HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Cyanocinnamyl alcohol → 3-Cyano-1-(2-formylethenyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Cyanocinnamyl alcohol | HCID 53735247 | — |
| Catalyst | HCID 178418406 | HCID 178418406 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 3-Cyano-1-(2-formylethenyl)benzene | HCID 54477214 | — |
Reaction Steps
A suspension of active manganese dioxide (20 g) in a solution of 3-cyanocinnamyl alcohol (Example 10(d), 4.0 g) in dichloromethane (100 ml) was stirred at room temperature for 16 hours. The mixture was filtered and the filtrate was evaporated to give the title product as a white solid, m.p. 100° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04963578 |
| Source dataset | uspto-grants-1990_10 |
| ORD ID | ord-fa711d74514f498180e3a1bd3aac99b7 |
| Source note | uspto-grants-1990_10 |