HCID 13741088, compound → 4-tert-Butyltoluene

HRID 1088907Notes

Reaction equation

HRID 1088907 reaction equation
N[C:2]1[CH:7]=[C:6]([C:8]([CH3:11])([CH3:10])[CH3:9])[CH:5]=[C:4](N)[C:3]=1[CH3:13]>C1(C)C=CC=CC=1>[CH2:2]=[C:3]([CH3:13])[CH3:4].[C:8]([C:6]1[CH:5]=[CH:4][C:3]([CH3:13])=[CH:2][CH:7]=1)([CH3:11])([CH3:10])[CH3:9]

Participants

4

Reactant 1

HCID 13741088HCID 13741088, compound

Product 2

HCID 73904-tert-ButyltolueneHCID 8255Isobutylene

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent2×

Procedure

The diamine, 2,6-diamino-4-t-butyltoluene, was prepared from toluene. Alkylation of toluene with isobutene gave p-t-butyltoluene which was then nitrated to give 2,6-dinitro-4-t-butyltoluene. Reduction of the dinitro compound produced the diamine.

Sources & evidence

ORD record
ord-35f3c19fb3224424ae13bd1c39c6b071
Source dataset
uspto-grants-1990_10
Patent number
US04963648

Reaction notes

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