HCID 14814223, compound → HCID 14814226, compound

HRID 1089262Notes

Reaction equation

HRID 1089262 reaction equation
[CH2:1]([O:8][CH2:9][C@H:10]([O:21]COC)[CH2:11][CH2:12][O:13][CH2:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>C(O)C>[CH2:1]([O:8][CH2:9][C@H:10]([OH:21])[CH2:11][CH2:12][O:13][CH2:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 1

HCID 14814223HCID 14814223, compound

Product 1

HCID 14814226HCID 14814226, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The (R)-isomer was prepared in an identical fashion from (R)-1,4-dibenzyloxy-2-(methoxymethoxy)-butane and had [α]D25 +7.7° (c 0.5 in ethanol).

Sources & evidence

ORD record
ord-4a5ea1432901438bb967b0851a69f55a
Source dataset
uspto-grants-1990_10
Patent number
US04965270

Reaction notes

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