Ammonia → HCID 19813651, compound

HRID 1089380Notes

Reaction equation

HRID 1089380 reaction equation
Cl[C:2]([N:4]([C:13]1[N:18]=[C:17]([CH3:19])[CH:16]=[C:15]([CH3:20])[N:14]=1)[C:5]1[CH:10]=[C:9]([Cl:11])[CH:8]=[CH:7][C:6]=1[Cl:12])=[O:3].[NH3:21]>C(Cl)(Cl)Cl>[Cl:12][C:6]1[CH:7]=[CH:8][C:9]([Cl:11])=[CH:10][C:5]=1[N:4]([C:13]1[N:18]=[C:17]([CH3:19])[CH:16]=[C:15]([CH3:20])[N:14]=1)[C:2]([NH2:21])=[O:3]

Participants

4

Reactant 2

HCID 222AmmoniaHCID 19813658HCID 19813658, compound

Product 1

HCID 19813651HCID 19813651, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

4.0 g (0.012 mole) of N-chlorocarbonyl-N-(4,6-dimethylpyrimidin-2-yl)-2,5-dichloroaniline are dissolved in 50 ml of chloroform. An excess of ammonia gas is introduced into the solution. When the exothermic reaction has subsided, the reaction mixture is washed twice with water, dried with magnesium sulfate and concentrated by evaporation.

Workup

  1. customWhen the exothermic reaction
  2. washthe reaction mixture is washed twice with water
  3. dry with materialdried with magnesium sulfate
  4. concentrationconcentrated by evaporation

Sources & evidence

ORD record
ord-1dd41e87eb0e4d5ea3e5f8ab026d1fca
Source dataset
uspto-grants-1990_10
Patent number
US04966622

Reaction notes

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