HCID 14856367, compound → HCID 14856375, compound

HRID 1089561Notes

Reaction equation

HRID 1089561 reaction equation
[CH3:1][S:2]([NH:5][C:6]1[CH:32]=[CH:31][C:9]2[O:10][CH2:11][CH2:12][N:13]([C:17](=O)[CH2:18][C:19]3[CH:24]=[CH:23][C:22]([NH:25][S:26]([CH3:29])(=[O:28])=[O:27])=[CH:21][CH:20]=3)[CH2:14][CH2:15][O:16][C:8]=2[CH:7]=1)(=[O:4])=[O:3].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:29][S:26]([NH:25][C:22]1[CH:21]=[CH:20][C:19]([CH2:18][CH2:17][N:13]2[CH2:12][CH2:11][O:10][C:9]3[CH:31]=[CH:32][C:6]([NH:5][S:2]([CH3:1])(=[O:3])=[O:4])=[CH:7][C:8]=3[O:16][CH2:15][CH2:14]2)=[CH:24][CH:23]=1)(=[O:27])=[O:28]

Participants

3

Reactant 2

HCID 14856367HCID 14856367, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 14856375HCID 14856375, compound

Procedure

In a manner similar to example 8, react 9-[(methylsulfonyl)amino]-4-[2-[4-[(methylsulfonyl)amino]phenyl]acetyl]-3,4,5,6-tetrahydro-2H-1,7,4-benzodioxazonine with lithium aluminum hydride to obtain the title compound.

Sources & evidence

ORD record
ord-df9570a62c1a4961ad536bde51e4153c
Source dataset
uspto-grants-1990_10
Patent number
US04966967

Reaction notes

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