Sulfur Dioxide → HCID 13497266, compound

HRID 1089662Notes

Reaction equation

HRID 1089662 reaction equation
P(Cl)(Cl)(Cl)(Cl)[Cl:2].[C:7]([CH:13]([C:16]#[N:17])[C:14]#[N:15])(=O)[C:8]([CH3:11])([CH3:10])[CH3:9].S(=O)=O>C(Cl)Cl>[Cl:2][C:7]([C:8]([CH3:11])([CH3:10])[CH3:9])=[C:13]([C:16]#[N:17])[C:14]#[N:15]

Participants

5

Reactant 3

HCID 1119Sulfur DioxideHCID 24819Phosphorus pentachlorideHCID 18424095(2,2-Dimethylpropanoyl)propanedinitrile

Product 1

HCID 13497266HCID 13497266, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Phosphorous pentachloride (86 g) was added slowly to a stirred suspension of the above pivaloylmalononitrile intermediate (a) (57 g) in methylene chloride (500 ml) and was allowed to stir at room temperature for 16 hours. Sulfur dioxide was passed through the solution for 20 minutes and the solvent was removed on a rotary evaporator. The residue was poured onto ice and filtered. The product was used without further purification.

Workup

  1. customthe solvent was removed on a rotary evaporator
  2. additionThe residue was poured onto ice
  3. filtrationfiltered
  4. customThe product was used without further purification

Sources & evidence

ORD record
ord-aace5495d403435696f0237602ba79d4
Source dataset
uspto-grants-1992_01
Patent number
US05079213

Reaction notes

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