Sodium Acetate → Benzenamine, N,N-diethyl-2-methoxy-

HRID 1089663Notes

Reaction equation

HRID 1089663 reaction equation
C(N[C:5]1[C:6]([O:16][CH3:17])=[C:7]([CH:13]=[CH:14][CH:15]=1)[N:8]([CH2:11][CH3:12])[CH2:9][CH3:10])(=O)C.C([O-])(=O)C.[Na+]>C(O)(=O)C.O>[CH3:17][O:16][C:6]1[C:7]([N:8]([CH2:9][CH3:10])[CH2:11][CH3:12])=[CH:13][CH:14]=[CH:15][CH:5]=1

Participants

5

Reactant 2

HCID 517045Sodium AcetateHCID 19915623HCID 19915623, compound

Product 1

HCID 116599Benzenamine, N,N-diethyl-2-methoxy-

Reagents, catalysts & solvents 2

HCID 176Acetic AcidSolventHCID 962WaterSolvent

Procedure

3-Acetamido-2-methoxy-N,N-diethylaniline (1.15 g) was dissolved in aqueous acetic acid (1:1 10 ml) and sodium acetate (5 g) was added. The solution was cooled in ice and the above diazonium solution was added slowly. After 15 minutes the solution was diluted with water and the precipitated dye was filtered off.

Workup

  1. temperatureThe solution was cooled in ice
  2. filtrationthe precipitated dye was filtered off

Sources & evidence

ORD record
ord-1bcb77cd4ad741e0a486adc3060b1ae5
Source dataset
uspto-grants-1992_01
Patent number
US05079213

Reaction notes

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