HCID 86744232, compound → HCID 86744231, compound

HRID 1089701Notes

Reaction equation

HRID 1089701 reaction equation
[N+:1]([C:4]1[CH:25]=[CH:24][C:7]([CH2:8][CH2:9][CH2:10][NH:11][CH2:12][CH2:13][CH2:14][C:15]2[CH:20]=[CH:19][C:18]([N+:21]([O-])=O)=[CH:17][CH:16]=2)=[CH:6][CH:5]=1)([O-])=O>C(O)C.[Pd]>[NH2:1][C:4]1[CH:5]=[CH:6][C:7]([CH2:8][CH2:9][CH2:10][NH:11][CH2:12][CH2:13][CH2:14][C:15]2[CH:16]=[CH:17][C:18]([NH2:21])=[CH:19][CH:20]=2)=[CH:24][CH:25]=1

Participants

4

Reactant 1

HCID 86744232HCID 86744232, compound

Product 1

HCID 86744231HCID 86744231, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A solution of N,N-bis-(4-nitrophenethyl)methylamine (1.2 g, 3.6 mmol) in ethanol (50 ml) containing 5% Pd/C (0.15 g) was stirred under a hydrogen atmosphere (50 p.s.i.) for 4 hours. The reaction mixture was filtered and the solvent evaporated to give the title compound as an oil, yield 1.0 g, which was used directly without further purification.

Workup

  1. filtrationThe reaction mixture was filtered
  2. customthe solvent evaporated

Sources & evidence

ORD record
ord-8c5b05031dde4beab8a75f57f5d3657d
Source dataset
uspto-grants-1992_01
Patent number
US05079248

Reaction notes

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