HRID1089915

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14476658

未命名化合物

结构：[Li]c1cc2cc(OC)ccc2n1S(=O)(=O)c1ccccc1

HCID178506645

未命名化合物

HCID178506647

未命名化合物

PRODUCTS

生成物

结构：COc1nccc(C(C)(O)c2cc3cnccc3n2S(=O)(=O)c2ccccc2)c1C(=O)N(C(C)C)C(C)C

HCID67917225

未命名化合物

PROCEDURE

实验过程

Starting from 1-benzenesulfonyl 2-lithio 5-aza indole and 4-acetyl 3-diisopropylaminocarbonyl 2-methoxy pyridine as reagent with electrophilic character, prepared according to paragraph (a) (stabilization reagent: tetramethylethylenediamine).

WORKUP

后处理

customprepared

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e6f7b330297040d9a8247eb15c40c8d5
来源数据集: uspto-grants-1992_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05079363
来源说明: uspto-grants-1992_01

反应 SMILES

[C:1]1([S:7]([N:10]2[C:18]3[C:13](=[CH:14][N:15]=[CH:16][CH:17]=3)[CH:12]=[C:11]2[Li])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]([C:23]1[CH:28]=[CH:27][N:26]=[C:25]([O:29][CH3:30])[C:24]=1[C:31]([N:33]([CH:37]([CH3:39])[CH3:38])[CH:34]([CH3:36])[CH3:35])=[O:32])(=[O:22])[CH3:21].C1(S(N2C3C(=CC(OC)=CC=3)C=C2[Li])(=O)=O)C=CC=CC=1>>[C:1]1([S:7]([N:10]2[C:18]3[C:13](=[CH:14][N:15]=[CH:16][CH:17]=3)[CH:12]=[C:11]2[C:20]([C:23]2[CH:28]=[CH:27][N:26]=[C:25]([O:29][CH3:30])[C:24]=2[C:31]([N:33]([CH:37]([CH3:39])[CH3:38])[CH:34]([CH3:36])[CH3:35])=[O:32])([OH:22])[CH3:21])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1