3-diethylaminocarbonyl 2-methoxy 4-(N-methoxy N-methylaminocarbonyl) pyridine → (1-Benzenesulfonyl 5-aza 2-indolyl) (3-diethylaminocarbonyl 2-methoxy 4-pyridyl)ketone
Reaction equation
[C:1]1([S:7]([N:10]2[C:18]3[C:13](=[CH:14][N:15]=[CH:16][CH:17]=3)[CH:12]=[C:11]2[Li])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:20]([N:22]([CH2:39][CH3:40])[C:23]([C:25]1[C:26]([O:37][CH3:38])=[N:27][CH:28]=[CH:29][C:30]=1[C:31](N(OC)C)=[O:32])=[O:24])[CH3:21]>>[C:1]1([S:7]([N:10]2[C:18]3[C:13](=[CH:14][N:15]=[CH:16][CH:17]=3)[CH:12]=[C:11]2[C:31]([C:30]2[CH:29]=[CH:28][N:27]=[C:26]([O:37][CH3:38])[C:25]=2[C:23]([N:22]([CH2:20][CH3:21])[CH2:39][CH3:40])=[O:24])=[O:32])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1Participants
3
Procedure
This compound was prepared according to the method described in Example 14c starting from 1-benzenesulfonyl 2-lithio 5-aza indole and 3-diethylaminocarbonyl 2-methoxy 4-(N-methoxy N-methylaminocarbonyl) pyridine.
Workup
- customThis compound was prepared
Sources & evidence
- ORD record
- ord-3b1610b08a57458eb9d3c8bb1c5423cf
- Source dataset
- uspto-grants-1992_01
- Patent number
- US05079363
Reaction notes
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