HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl (ethoxymethylene)malonate → HCID 19914484, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl (ethoxymethylene)malonate | HCID 6871 | — |
| Reactant | 4-methoxy-2-(methylthio)aniline | HCID 11147966 | — |
| Product | HCID 19914484 | HCID 19914484 | 81.5% |
Reaction Steps
4-Methoxy-2-methylsulfenylaniline (1.5 g) and diethyl ethoxymethylenemalonate (1.9 g) were reacted in the same manner as in Experimental Example 1 to obtain 3-ethoxycarbonyl-6-methoxy-8-methylsulfenyl-4(1H)-quinolone (2.1 g). The compound (1.3 g) was subjected to hydrolysis and decarboxylation in the same manner as in Experimental Example 2 to obtain 6-methoxy-8-methylsulfenyl-4(1H)-quinolone (compound 30, 0.95 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05081121 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-e342e284f22f46e2ac167fc1c2370bba |
| Source note | uspto-grants-1992_01 |