Hexadecanethiol → HCID 57254888, compound

HRID 1090210Notes

Reaction equation

HRID 1090210 reaction equation
[CH2:1]([SH:17])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[CH2:18]([O:21][CH2:22][C:23]([CH2:34][O:35][CH2:36][CH:37]=[CH2:38])([CH2:29][O:30][CH2:31][CH:32]=[CH2:33])[CH2:24][O:25][CH2:26][CH:27]=[CH2:28])[CH:19]=[CH2:20]>>[CH2:1]([S:17][CH2:38][CH2:37][CH2:36][O:35][CH2:34][C:23]([CH2:24][O:25][CH2:26][CH2:27][CH2:28][S:17][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])([CH2:29][O:30][CH2:31][CH2:32][CH2:33][S:17][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:22][O:21][CH2:18][CH2:19][CH2:20][S:17][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 18015HexadecanethiolHCID 738553,3'-((2,2-Bis((allyloxy)methyl)-1,3-propanediyl)bis(oxy))dipropene

Product 1

HCID 57254888HCID 57254888, compound

Procedure

The procedure used was identical to that set forth in Example 4, except that 107 g of hexadecyl mercaptan (0.417 moles) was reacted with 29.64 g of pure pentaerythritol tetraallyl ether (0.1 moles). The crude product was recrystallized three times in 300 ml of hexane yielding 57 g of white solid having a melting point 55°-57° C. The elemental analysis found: C-73.4%, H-11.9%, S-10.0%, calculated for C88H164S4 (theoretical C-73.12%, H-12.4%, S-9.64% and O-4.81%).

Workup

  1. customThe crude product was recrystallized three times in 300 ml of hexane yielding 57 g of white solid

Sources & evidence

ORD record
ord-df457c122f6e4e67959eb29e535468a2
Source dataset
uspto-grants-1992_01
Patent number
US05081169

Reaction notes

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