HuagongsheHuagongshe Chemistry Print Report · For research reference only
Pyridine → HCID 178448836, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Pyridine | HCID 1049 | — |
| Reactant | Phosphorus sulfide (P2S5) | HCID 14817 | — |
| Reactant | 3-(1H-Imidazol-1-yl)butan-1-amine | HCID 13952862 | — |
| Reactant | HCID 178527781 | HCID 178527781 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 178448836 | HCID 178448836 | — |
Reaction Steps
The Wolff-Kishner-Huang Minlon reductive procedure is applied to 6-benzoylbenz(cd)indol-2-one to yield 6-benzylbenz(cd)indol-2(1H)-one which is converted to 6-benzylbenz(cd)indol-2-thiol by P2S5 in refluxing pyridine. The reaction of the latter compound with 3-(1H-imidazol-1-yl)butanamine and mercuric acetate in refluxing ethanol, under the conditions of Example 55, leads to the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05081131 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-625c06d903114cd2bb81a45ec4b0fed9 |
| Source note | uspto-grants-1992_01 |