HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Hydroxide → 3,4-Dihydro-2H-1,4-benzoxazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 2H-1,4-benzoxazin-3(4H)-one | HCID 72757 | — |
| Reactant | Diboron | HCID 6328200 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 3,4-Dihydro-2H-1,4-benzoxazine | HCID 585096 | — |
Reaction Steps
3,4-Dihydro-3-oxo-1,4(2H)-benzoxazine was refluxed for several hours in one equivalent of diborane in tetrahydrofuran. Excess sodium hydroxide solution was added, the product was extracted with ether and the solvent was evaporated to give the title compound as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05081242 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-56440bdad44c40ccb092f6327e052940 |
| Source note | uspto-grants-1992_01 |