HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → p-Trimethylgermylacetophenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Benzenesulfonic acid, 4-methyl-, compd. with pyridine (1:1) | HCID 466102 | — |
| Reactant | 2-(4-Trimethylgermylphenyl)-2-methyl-1,3-dioxolane | HCID 14605651 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | p-Trimethylgermylacetophenone | HCID 14605652 | — |
Reaction Steps
A solution of 420 mg (1.5 mmol) of 2-(4-trimethylgermylphenyl)-2-methyl-1,3-dioxolane and 56 mg (0.19 mmol) of pyridinium p-toluenesulfonate (PPTS) in 1.35 g (62.5 mmol) of water and 10 ml of acetone was refluxed for 2 hours and stirred at room temperature for 1.5 days. The reaction mixture was extracted with petroleum ether. The extract was washed successively with 2N hydrochloric acid, water and sat.aq.NaHCO3, dried and evaporated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05081271 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-00b28213e0744daa8848936d822b4400 |
| Source note | uspto-grants-1992_01 |