Tributylstannane → HCID 19915379, compound

Participants

Reaction Conditions

Reaction Steps

A solution of 8.6 grams (0.028 mole) of 2,4-dibromo-4,4-difluorobutyl acetate and 8.2 ml (0.028 mole) of tributyltin hydride in 15 ml of xylene was stirred, and 0.01 gram of 1,1'-azobisisobutyronitrile was added. The reaction mixture was warmed to 120° C. where it was stirred for 18 hours. The reaction mixture was distilled under reduced pressure, yielding 0.4 gram of 4-bromo-4,4-difluorobutyl acetate; b.p. 40°-55° C./1.8 mm. The nmr spectrum was consistent with the proposed structure.

Provenance & Evidence