Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | N,N-Dimethyl-2-(2-nitrophenyl)ethen-1-amine | HCID 54442712 | — |
| Catalyst | Cuprous chloride | HCID 62652 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-Nitrobenzaldehyde | HCID 11101 | 87.2% |
Reaction Steps
20 g of β-dimethylamino-2-nitrostyrene, 1 g of CuCl and 300 ml of DMF were initially introduced into a 300 ml autoclave equipped with an aerating stirrer. The autoclave was heated to 50° C. and pressurized to 10 bar with air, and a pressure of 20 bar was then maintained using oxygen. After 2 h, the experiment was discontinued and 87.2% of o-nitrobenzaldehyde was obtained after working-up.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05082976 |
|---|
| Source dataset | uspto-grants-1992_01 |
|---|
| ORD ID | ord-7dd8230093a4486b9eef52669ccd0d27 |
|---|
| Source note | uspto-grants-1992_01 |
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