HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 2-Cyanobenzaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | beta-Dimethylamino-2-cyanostyrene | HCID 54125819 | — |
| Catalyst | Cuprous chloride | HCID 62652 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-Cyanobenzaldehyde | HCID 101209 | — |
Reaction Steps
8.6 g of β-dimethylamino-2-cyanostyrene were dissolved in 100 ml of DMF. 0.25 g of CuCl was added and the mixture was aerated for 4 h at 35°-40° C. using oxygen. After the customary aqueous work-up, o-cyanobenzaldehyde was obtained as the product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05082976 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-a87b31f6b45044d0931aa5839e0e3541 |
| Source note | uspto-grants-1992_01 |