Ammonia → HCID 15027495, compound

Participants

Reaction Steps

To a stirred mixture of 9.4 g of the above benzamide, 100 ml of methanolic ammonia and 100 ml of methanol was added dropwise, in increments, 25 ml of 30% hydrogen peroxide. After stirring overnight, the solid was collected, partially dissolved in 500 ml of hot acetonitrile and filtered. The filtrate was chilled, the solid collected and recrystallized from 200 ml of acetonitrile, giving 1.8 g of the desired product as white crystals, mp 185°-187° C.

Provenance & Evidence