HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → HCID 178425849, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | N-[[[2-(Aminocarbonyl)-4-methylphenyl]amino]thioxomethyl]-4-methylbenzamide | HCID 15135527 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 178425849 | HCID 178425849 | 10.7% |
Reaction Steps
To a stirred mixture of 5.2 g of the above benzamide, 100 ml of methanolic ammonia and 100 ml of methanol was added dropwise, in increments, 20 ml of 30% hydrogen peroxide. After stirring 48 hours, the solid was collected, partially dissolved in 400 ml of hot acetonitrile and filtered. The filtrate was chilled, giving 0.5 g of the desired product as white crystals, mp 242°-244° C. (dec.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05084457 |
| Source dataset | uspto-grants-1992_01 |
| ORD ID | ord-58c14a0b0e12498ea7860ca913a5a2a4 |
| Source note | uspto-grants-1992_01 |