化工社化工社 化学情報印刷レポート · 研究参考用
Methanol → 8-[1,1'-Biphenyl]-4-yl-7,10-diphenylfluoranthene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methanol | HCID 887 | — |
| 反応物 | 1,2-Dichlorobenzene | HCID 7239 | — |
| 反応物 | 4-Ethynyl-1,1'-biphenyl | HCID 34464 | — |
| 反応物 | 7,9-Diphenyl-8H-cyclopenta[a]acenaphthylen-8-one | HCID 267145 | — |
| 生成物 | 8-[1,1'-Biphenyl]-4-yl-7,10-diphenylfluoranthene | HCID 59844130 | — |
反応手順
Acecyclone (12 g, 33.6 mMole) and 4-biphenylacetylene (9.0 g, 50.5 mMole) were heated to gentle reflux in ortho-dichlorobenzene (100 ML) for 2 hours. The reaction was then cooled, treated with methanol (20 mL) and stirred at room temperature for 1 hour. The resulting yellow solid was filtered off, washed well with methanol and dried. Yield of product ETM1, 17.4 g. Before use in device fabrication, ETM1 was sublimed at 220° C./10−3 mm Hg.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08129039B2 |
| 出典データセット | uspto-grants-2012_03 |
| ORD ID | ord-815d6812e8564b029f220ae8bf2578aa |
| 出典メモ | uspto-grants-2012_03 |