HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminumhydride → 1021392-76-6
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminumhydride | HCID 21225700 | — |
| Reactant | Dichloromethane methanol ammonium hydroxide | HCID 21896990 | — |
| Reactant | HCID 43145163 | HCID 43145163 | — |
| Product | 1021392-76-6 | HCID 43519495 | — |
Reaction Steps
This material was obtained in analogy to example 65, step A] from known 3-amino-1-benzyl-piperidine-3-carbonitrile (CAS 153931-24-9, 1.23 g) by reduction with diisobutylaluminiumhydride (20% in toluene, 14.2 mL) as a colorless glass (458 mg) after silica gel chromatography (DCM/methanol/NH4OH 9:1:0.1). MS (ESI): 220.3 (MH+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08129423B2 |
| Source dataset | uspto-grants-2012_03 |
| ORD ID | ord-3e71f2d589ff4e5393fe1fbf90e61e43 |
| Source note | uspto-grants-2012_03 |