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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1094476Generated: October 30, 2026

Azobisisobutyronitrile → Prop-2-enenitrile--ethenylbenzene (1/1)

https://huagongshe.com/reaction/1094476

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAzobisisobutyronitrileHCID 6547—
ReactantStyreneHCID 7501—
ReactantAcrylonitrileHCID 7855—
ReactantTricalcium PhosphateHCID 24456—
SolventWaterHCID 962—
ProductProp-2-enenitrile--ethenylbenzene (1/1)HCID 62696—

Reaction Steps

75 parts by weight of styrene, 25 parts by weight of acrylonitrile, and 120 parts by weight of deionized water are mixed. 0.2 parts by weight of azobisisobutylonitrile (AIBN), 0.4 parts by weight of tricalciumphosphate and 0.2 parts by weight of mercaptan-containing chain transfer agent are added into the mixture. The resultant solution is heated from room temperature to 80° C. for 90 minutes and then kept for 180 minutes at this temperature to obtain a styrene-acrylonitrile copolymer resin (SAN). The styrene-acrylonitrile copolymer resin (SAN) is washed, dehydrated and dried to obtain a styrene-acrylonitrile copolymer resin (SAN) in a powder form. The prepared styrene-acrylonitrile copolymer resin (SAN) has a weight average molecular weight (Mw) of about 90,000 g/mol.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08133946B2
Source datasetuspto-grants-2012_03
ORD IDord-ce784d56a4cf4ce3a7c5ea275c984c28
Source noteuspto-grants-2012_03